![]() ![]() The position of the eutectic equilibrium point is found to shift toward a low-melting-point component by 5-10%, and the eutectic point temperature is lightly overestimated in comparison with the experimental results and the FactSage data. The discrepancies between the calculated and published data become more noticeable for systems containing larger and more polarizable cations. The error in describing the liquidus lines in the phase diagrams of the fluoride mixtures with the use of the tabulated ionic radii and polarizabilities is at most 15% as compared to the available FactSage data. The liquidus lines in the binary phase diagrams LiF-NaF, LiF-KF, NaF-KF, NaF-CsF, and KF-CsF of the eutectic type are calculated. The linear combination of 0.6667 A + 0.3333 B 0.6667 ☊ + 0.3333 ☋ represents the minimum Gibbs energy for the fixed system composition xB 0. Figure 1.4 shows the situation for an equilibrium between pure A and pure B. A thermodynamic perturbation theory model is developed to take into account the additional charge-dipole contribution to the free energy of molten alkali halide systems, and it is used to describe the melt-crystal equilibria in binary salt mixtures with common anions. Download scientific diagram Equilibrium Fe-Zn phase diagram calculated with FactSage from publication: Role of liquid Zn and -Fe(Zn) on liquid metal embrittlement of medium Mn steel: An ex. 1.4 The equilibrium situation between pure A and B in a binary system exhibiting the phase A, AB, B and liq. ![]()
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